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By Armando J. L. Pombeiro

A modern compilation of modern achievements in organometallic chemistry

The prestigious foreign convention on Organometallic Chemistry (ICOMC) was once introduced in 1963, offering a discussion board for researchers from worldwide to percentage their findings and discover new paths to improve our wisdom and alertness of organometallic chemistry. The twenty fifth ICOMC, held in Lisbon in 2012, accrued greater than 1,200 contributors from fifty four international locations. This quantity celebrates the twenty fifth Silver variation and the fiftieth Gold yr of the ICOMC.

Featuring contributions from invited twenty fifth ICOMC audio system, Advances in Organometallic Chemistry and Catalysis highlights fresh achievements and new and rising components of analysis within the box. Its seven sections conceal:

  • Activation and Functionalization of Carbon unmarried Bonds and Small Molecules
  • Organometallic Synthesis and Catalysis
  • Organometallic Polymerization Catalysis
  • Organometallic Polymers and Materials
  • Organometallic Chemistry and Sustainable Energy
  • Bioorganometallic Chemistry
  • Organometallic Electrochemistry

Chapters speak about basic underlying strategies, provide illustrative examples and situations, and discover destiny avenues for persevered examine. Readers will notice easy rules and houses of organometallic compounds, response mechanisms, and specified descriptions of present purposes. jointly, those chapters underscore the flexibility, richness, and strength of contemporary organometallic chemistry, together with its interrelationships with different clinical disciplines.

All the contributions are commonly referenced, delivering a gateway to an important unique examine papers and studies in organometallic chemistry. providing a modern knowing of organometallic chemistry and its many purposes, Advances in Organometallic Chemistry and Catalysis is suggested for all researchers within the box, from scholars to complex investigators.Content:
Chapter 1 Organometallic Complexes as Catalysts in Oxidation of CH Compounds (pages 1–13): Georgiy B. Shul'pin
Chapter 2 towards Functionalization of Alkanes below Environmentally Benign stipulations (pages 15–25): Armando J. L. Pombeiro
Chapter three Self‐Assembled Multicopper Complexes and Coordination Polymers for Oxidation and Hydrocarboxylation of Alkanes (pages 27–38): Alexander M. Kirillov, Marina V. Kirillova and Armando J. L. Pombeiro
Chapter four Activation of C–O and C–F Bonds through Pincer–Iridium Complexes (pages 39–57): Jason Hackenberg, Karsten Krogh‐Jespersen and Alan S. Goldman
Chapter five Functionalization of sp2 and sp3 Carbon facilities Catalyzed through Polyoxometalates and Metalloporphyrins (pages 59–71): Mário M. Q. Simões, Isabel C. M. S. Santos, Maria Graça P. M. S. Neves, Ana M. V. Cavaleiro and José A. S. Cavaleiro
Chapter 6 Quasi‐Borinium Cation in response to Cobalt Bis(Dicarbollide): Its Lewis Acidity and C–H and C–X Bond Activation (pages 73–79): V. I. Bregadze, I. B. Sivaev, I. D. Kosenko, I. A. Lobanova, Z. A. Starikova and that i. A. Godovikov
Chapter 7 Transition‐Metal‐Promoted Functionalization of Carboranes (pages 81–96): Zaozao Qiu and Zuowei Xie
Chapter eight vulnerable Interactions and M–H Bond Activation (pages 97–109): Elena Shubina, Natalia Belkova, Oleg Filippov and Lina Epstein
Chapter nine Complexes with Protic N‐Heterocyclic Carbene (NR,NH‐NHC) Ligands (pages 111–132): F. Ekkehardt Hahn
Chapter 10 Cyclopentadienyl‐Functionalized N‐Heterocyclic Carbene Complexes of Iron and Nickel: Catalysts for mark downs (pages 133–143): Beatriz Royo
Chapter eleven Palladium‐(Acyclic Diaminocarbene) Species as replacement to Palladium‐(Nitrogen Heterocyclic Carbenes) in Cross‐Coupling Catalysis (pages 145–155): Vadim P. Boyarskiy, Konstantin V. Luzyanin and Vadim Yu. Kukushkin
Chapter 12 Synthesis of Metallocenes through Metathesis in steel Coordination Spheres (pages 157–170): Antoni Pietrzykowski and WŁodzimierz Buchowicz
Chapter thirteen Metal‐Mediated [2+3] Dipolar Cycloaddition to Substrates with CN Triple Bond: contemporary Advances (pages 171–183): Konstantin V. Luzyanin and Maxim L. Kuznetsov
Chapter 14 Coordination Chemistry of Oxazoline/Thiazoline‐Based P,N Ligands (pages 185–198): Shuanming Zhang, Roberto Pattacini and Pierre Braunstein
Chapter 15 “Click” Copper Catalyzed Azide–Alkyne Cycloaddition (CUAAC) in Aqueous Medium (pages 199–206): Joaquín García‐Álvarez and José Gimeno
Chapter sixteen Organogold Catalysis: Homogeneous Gold‐Catalyzed modifications for a Golden Jubilee (pages 207–225): Fabien Gagosz
Chapter 17 Vanadium(IV) Complexes Derived from fragrant O‐Hydroxyaldehydes and Tyrosine Derivatives: Catalytic evaluate in Sulfoxidations (pages 227–232): João Costa Pessoa, Isabel Correia and Pedro Adão
Chapter 18 Microwave‐Assisted Catalytic Oxidation of Alcohols to Carbonyl Compounds (pages 233–245): Yauhen Yu. Karabach, Maximilian N. Kopylovich, Kamran T. Mahmudov and Armando J. L. Pombeiro
Chapter 19 Oxidation of Glycerol with Hydrogen Peroxide Catalyzed via steel Complexes (pages 247–257): Dalmo Mandelli, Wagner A. Carvalho, Lidia S. Shul'pina, Alexander M. Kirillov, Marina V. Kirillova, Armando J. L. Pombeiro and Georgiy B. Shul'pin
Chapter 20 Involvement of an Acetato Ligand within the Reductive removal Step of the Rhodium‐Catalyzed Methanol Carbonylation (pages 259–268): Duc Hanh Nguyen, Nicolas Lassauque, Thomas Davin, Laurent Maron, Carole Le Berre, Philippe Serp and Philippe Kalck
Chapter 21 Half‐Sandwich Rhodium(III), Iridium(III), and Ruthenium(II) Complexes with Ancillary Pyrazole‐Based Ligands (pages 269–284): Claudio Pettinari, Riccardo Pettinari, Corrado Di Nicola and Fabio Marchetti
Chapter 22 Carbon–Scorpionate Complexes in Oxidation Catalysis (pages 285–294): Luísa M. D. R. S. Martins and Armando J. L. Pombeiro
Chapter 23 towards Chemoselective Bioconjugative Desulfitative Catalysis (pages 295–303): Lanny S. Liebeskind and Ethel C. Garnier‐Amblard
Chapter 24 Sulfoxide Redox Chemistry with Molybdenum Catalysts (pages 305–314): Maria José Calhorda and Luis F. Veiros
Chapter 25 a brand new kinfolk of Zirconium Complexes Anchored by means of Dianionic Cyclam‐Based Ligands: Syntheses, constructions, and Catalytic functions (pages 315–323): Ana M. Martins, Rui F. Munhá, Luis G. Alves and Shanmuga Bharathi
Chapter 26 Metal–Organo Multicatalysis: An rising idea (pages 325–342): Alexandre F. Trindade, João N. Rosa, Fábio M. F. Santos and Pedro M. P. Gois
Chapter 27 Coordinative Chain move Polymerization and Copolymerization via infrequent Earth Organometallic Catalysts for the Synthesis of Tailor‐Made Polymers (pages 343–358): Marc Visseaux, Thomas Chenal and Philippe Zinck
Chapter 28 Charge‐Neutral and Cationic Complexes of enormous Alkaline Earths for Ring‐Opening Polymerization and fantastic chemical compounds Catalysis (pages 359–378): Jean‐François Carpentier, Bo Liu and Yann Sarazin
Chapter 29 Organometallic Polymers (pages 379–405): Manuel Serrano‐Ruiz, Franco Scalambra and Antonio Romerosa
Chapter 30 From Serendipity to Porosity:Synthesis and Reactivity of Coordination Polymers in line with Copper Trinuclear Triangular Motifs (pages 407–419): Luciano Pandolfo
Chapter 31 Organometallic Nanoparticles (pages 421–436): Patricia Lara, Karine Philippot, Lise‐Marie Lacroix, Sébastien Lachaize, Nikos Liakakos, Katerina Soulantica and Bruno Chaudret
Chapter 32 Organometallic Compounds within the Synthesis of recent fabrics: outdated Ligands, New tips (pages 437–444): Piotr Sobota and Łukasz John
Chapter 33 The function of Organometallic Complexes within the Synthesis of formed Carbon fabrics (pages 445–458): Neil J. Coville and Edward N. Nxumalo
Chapter 34 steel Catalysis in Fullerene Chemistry (pages 459–472): Salvatore Filippone, Enrique E. Maroto, Ángel Martín‐Domenech and Nazario Martín
Chapter 35 Organometallic Complexes of Sumanene (pages 473–483): Toru Amaya and Toshikazu Hirao
Chapter 36 Advances in Luminescent Tetracoordinate Organoboron Compounds (pages 485–492): D. Suresh and Pedro T. Gomes
Chapter 37 Mechanochemistry: a device within the Synthesis of Catalysts, Metallodrugs, and Metallopharmaceuticals (pages 493–499): Vânia André, Clara S. B. Gomes and M. Teresa Duarte
Chapter 38 Organometallic Compounds for Dye‐Sensitized sunlight Cells (DSSC) (pages 501–511): Delele W. Ayele, Wei‐Nein Su, John Rick, Hung‐Ming Chen, Chun‐Jern Pan, Nibret G. Akalework and Bing‐Joe Hwang
Chapter 39 man made Photosynthesis for the Conversion of huge Volumes of Carbon Dioxide into Energy‐Rich Molecules: Saving Fossil Fuels by way of Recycling Carbon (pages 513–527): Michele Aresta and Angela Dibenedetto
Chapter forty Ionic drinks for Hydrogen garage: possibilities for Organometallic Chemistry (pages 529–541): Martin H. G. Prechtl and Sebastian Sahler
Chapter forty-one steel Carbonyls for Co‐Based cures: demanding situations and Successes (pages 543–561): Carlos C. Romão and Helena L. A. Vieira
Chapter forty two The Ferrocifen relatives as effective and Selective Antitumor Compounds: Mechanisms of motion (pages 563–580): Gérard Jaouen and Siden Top
Chapter forty three at the music to melanoma remedy: Paving New methods with Ruthenium Organometallics (pages 581–587): Tânia S. Morais and M. Helena Garcia
Chapter forty four Organometallic Chemistry of Rhenium and Technetium Fueled via Biomedical functions (pages 589–604): António Paulo, Goreti Ribeiro Morais and Isabel Santos
Chapter forty five Metal‐Based Indolobenzazepines and Indoloquinolines: From reasonable CDK Inhibitors to power Antitumor medicines (pages 605–617): Michael F. Primik, Lukas okay. Filak and Vladimir B. Arion
Chapter forty six Metal‐Based Chelates and Nanosystems as MRI distinction brokers (pages 619–630): Sara Figueiredo and Carlos F. G. C. Geraldes
Chapter forty seven Electrochemistry and Supramolecular Interactions of “Ferrocifen” Anticancer medicines with Cyclodextrins and Lipid Bilayers: An Electrochemical evaluation (pages 631–651): Olivier Buriez, Eric Labbé and Christian Amatore
Chapter forty eight Electrochemistry of Fischer Aminocarbene Complexes: results of constitution on Redox homes, Electron Distribution, and response Mechanisms (pages 653–665): Jiří Ludvík and Irena Hoskovcová
Chapter forty nine Electron Transfer‐Induced Coordination alterations in Organometallic Complexes with Noninnocent Hemilabile Ligands (pages 667–675): Wolfgang Kaim, Martina Bubrin and Ralph Hübner
Chapter 50 Redox Potential–Structure Relationships and Parameterization in Characterization and identity of Organometallic Compounds (pages 677–690): M. Fátima C. Guedes da Silva and Armando J. L. Pombeiro
Chapter fifty one Endohedral Metallofullerenes this day: an increasing number of flexible Ships in Multiform Bottles—Electrochemistry of X‐Ray characterised Monometallofullerenes (pages 691–702): Fabrizia Fabrizi de Biani and Piero Zanello

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Extra resources for Advances in Organometallic Chemistry and Catalysis: The Silver/Gold Jubilee International Conference on Organometallic Chemistry Celebratory Book

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Res. 2012, 45 , 803; (c) Sigman, M. ; Werner, E. W. Acc. Chem. Res. 2012, 45 , 874; (d) Hashiguchi, B. ; Bischof, S. ; Konnick, M. ; Periana, R. A. Acc. Chem. Res. 2012, 45 , 885; (e) Cavaliere, V. ; Mindiola, D. J. Chem. Sci. 2012, 3 , 3356–3365. 5. Shilov, A. ; Shul’pin, G. B. Chem. Rev. 1997, 97 , 2879. 6. ; Parent, A. ; Crabtree, R. ; Eisenstein, O. ACS Catal. 2012, 2 , 208. 7. (a) Shul’pin, G. ; Druzhinina, A. N. React. Kinet. Catal. Lett. 1991, 44 , 387; (b) Shul’pin, G. ; Druzhinina, A. N.

B. J. Catal. 2009, 268 , 26. Kirillova, M. ; Kuznetsov, M. ; Kozlov, Y. ; Shul’pina, L. ; Pombeiro, A. J. ; Shul’pin, G. B. ACS Catal. 2011, 1 , 1511. Shul’pin, G. ; Kozlov, Y. ; Nizova, G. ; Kulikova, V. S.. J. Chem. , Perkin Trans. 2001, 2 , 1351. Kozlov, Y. ; Romakh, V. ; Shul’pin, G. B. J. Phys. Chem. A 2007, 111 , 7736. Khaliullin, R. ; Bell, A. ; Head-Gordon, M. J. Phys. Chem. B 2005, 109 , 17984. REFERENCES 46. 47. 48. 49. 50. 51. 52. 53. 54. 55. 56. 57. 58. 59. 60. 61. 62. 63. 64. 65. 66.

J. ; Shul’pin, G. B. J. Catal. 2009, 267 , 140. Kirillova, M. ; Kozlov, Y. ; Shul’pina, L. ; Lyakin, O. ; Kirillov, A. ; Talsi, E. ; Pombeiro, A. J. ; Shul’pin, G. B. J. Catal. 2009, 268 , 26. Kirillova, M. ; Kuznetsov, M. ; Kozlov, Y. ; Shul’pina, L. ; Pombeiro, A. J. ; Shul’pin, G. B. ACS Catal. 2011, 1 , 1511. Shul’pin, G. ; Kozlov, Y. ; Nizova, G. ; Kulikova, V. S.. J. Chem. , Perkin Trans. 2001, 2 , 1351. Kozlov, Y. ; Romakh, V. ; Shul’pin, G. B. J. Phys. Chem. A 2007, 111 , 7736. Khaliullin, R.

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