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By Boy Cornils, Wolfgang A. Herrmann

Eventually as softcover: Homogeneous catalysis is the good fortune tale of organometallic chemistry. because the discovery of hydroformylation by way of O. Roelen in 1938, catalytic functions have cleared the path of organometallic compounds in undefined. Bulk and positive chemical substances, or even normal items are being produced through homogeneous organometallic catalysis. the large breadth of this subject in view of either uncomplicated learn and commercial program is met congenially during this instruction manual edited together through W. A. Herrmann (Technical collage Munich) and B. Cornils (Hoechst AG, Frankfurt). The record of over ninety individuals reads like a who-is-who in organometallic chemistry and homogeneous catalysis. during this guide, specialists will locate the present state of the art of their box and complicated scholars will enjoy the concise therapy of vital catalytic reactions and strategies. With its balanced presentation of the really interdisciplinary subject and its awesome editor- and authorship, the 'Cornils/Herrmann' is past universal criteria.

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1968, 49, 337. [80] A. ), Deutsche Nobelpreistrager, Moos & Partner, Munich, 1987. [81] (a) G. Natta, Chim. Ind. (Milan), 1942, 24, 389; G . Natta, E. Beati, ibid. 1945, 27, 84; G. Natta, P. Pino, ibid. 1949, 31, 109, 111; (b) G . Natta, P. Corradini, Atti Acad. Naz. Lincei Mem. CI. Sci. Fis. Mat. Nat. Sez. II 1955, 5, 73: (c) Montecatini (G. Natta, P. Pino, G. 712 (1954/1955); (d) G. Natta, Angew. Chem. 1956, 68, 393. F. Young, G. Wilkinson, Chem. Commun. 1965, 131; J. A. Osborn, F. H . Jardine, J.

It may be considered ironic that as early as 1969 a nearly complete description of the characteristic features of the subsequently presented LPO technology had been published by Monsanto researchers [5]. The company decided at that stage not to deal with hydroformylation any longer, but instead they concentrated on the development of the nowadays well-known acetic acid process (using modified rhodium carbonyl as catalyst); cf. 1 [6]. Compared with the cobalt technology, considerable advances had been established in the second-generation processes, especially with respect to material and energy utilization, so there was not much room left for further improvement.

Haggin, Chem. Eng. News 1994 (Oct. lo), 28. [47] E . Wiebus, B. -Tech. 1994, 66, 916; CHEMTECH 1995,25, 33. [48] E . Bayer, V Schurig, Angew. , Int. Ed. Engl. 1975, 14, 493; L. W. Grosser, W. H . Knoth, G . W. Parshall, J. Mol. Catal. 1977, 2, 253. 24 1 Introduction [49] Ruhrchemie AG (W. Greb. J. Hibbel, J. 953 (1987); Hoechst AG (H. 615 (1989). [50] A . Behr, W. Keim, Erdol, Erdgas, Kohle 1987,103, 126. [51] G . W. Parshall, S. D. , Wiley, New York, 1992. [52] L. H. ), Homogeneous Catalysis with Metal Phosphine Complexes, Plenum Press, New York, 1983.

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