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By Helmut Bauer, Jürgen Faust, Rolf Froböse, Johannes Füssel, Ulrich Krüerke, Manfred Kunz, Herman Mihran Somer (auth.), Rolf Froböse, Johannes Füssel (eds.)

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Chern. Soc. 105 [1983] 4550/5). 1 Complexes with Alkynes Copper(O) Complexes with C2H2 n: Complexes (C2 H2)"Cu and (C2D2)nCu are stable only in matrices at low temperatures. , in resistively heated tantalum cells) and codeposited with C2 H2 (or C2D2 ) and Ar, Ne, or adamantane [2, 5, 6, 8]. Cu atoms give a very rich ESR spectrum with C2H2 . In addition to the high-field doublet due to 63Cu and 65Cu, the spectrum reveals the presence of C2 R2Cu and (C 2R2hCu (R = H or D) species. The relative amounts vary with the Cu:C 2H2 or Cu:C 2D2 ratio [2].

Gmelin Handbook Cu-Org. Comp. J. (J. Am. Chern. Soc. 71 [1949]1723/4). M. (J. Am. Chern. Soc. 71 [1949] 2379/80). E. (J. Am. Chern. Soc. 71 [1949] 2381/3). , Ogura, T. (lnorg. Chern. 21 [1982] 475/9). E. (J. Am. Chern. Soc. 71 [1949] 3906/9). , Phillips Petroleum Co. S. 2526971 [1950]). , Phillips Petroleum Co. S. 2557923 [1951]). , Phillips Petroleum Co. S. 2589960 [1952]). D. (Diss. Vanderbilt Univ. 1957, pp. 1/191; Diss. Abstr. A. 1957 16182). , Eichler, S. (Chern. Ber. 95 [1962] 260/7). E. (lnorg.

Chern. 22 [1983] 2892/5). , Mackor, A. (Tetrahedron Letters 1978 2321/4). , Mackor, A. (Rec. Trav. Chim. 98 [1979] 423/4). M. (Diss. Univ. Utrecht 1979). , Mackor, A. (Tetrahedron Letters 21 [1980] 415/8). , Mackor, A. (J. Am. Chern. Soc. 103 [1981] 6901/4). , Mackor, A. (Tetrahedron Letters 38 [1982)1311/9). , Eichler, S. (Chern. Ber. 95 [1962] 260/7). K. (J. Am. Chern. Soc. 95 [1973]1889/97). , Michl, J. (J. Am. Chern. Soc. 105 [1983) 4550/5). 5 Anions of the Types [2LCuCl2]- and [2LCuCl:J 2 - The following anions are formed in aqueous HCL solutions of CuCL and the alkenes 2 L.

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